
Tintypes, patented in 1856 by Hamilton Smith, were another medium that heralded the birth of photography. A thin sheet of iron was used to provide a base for light-sensitive material, yielding a positive image.
Photography advanced considerably when sensitized materials could be coated on plate glass. The first glass negatives were wet plate. They had to be developed quickly before the emulsion dried. (In the field this meant carrying along a portable process had been invented and patented which freed the photographer from the necessity of developing each print immediately.)